| Novel Synthetic Method for Triacetylbenzene |
| |
| 引用本文： | Bin ZHANG Yong GAO Jian Li LI Zhen SHI. Novel Synthetic Method for Triacetylbenzene[J]. 中国化学快报, 2006, 17(9): 1165-1168 |
| |
| 作者姓名： | Bin ZHANG Yong GAO Jian Li LI Zhen SHI |
| |
| 作者单位： | Bin ZHANG，Yong GAO，Jian Li LI，Zhen SHI Department of Chemistry，Northwest University，Xi′an 710069 |
| |
| 摘 要： | Triketones are an important class of compounds in view of the distinct structure feature and wide utility in macromolecular material, organic synthesis and coordination chemistry1. The synthetic method for preparing symmetrical triketones 1, 3, 5- triacetylbenzene reported by Robert et al. is via condensation of acetone with ethyl formate followed by the trimerization of the intermediate acetylacetaldehyde2. We reported the reaction of benzimidazolium salts with Grignard reagents, providing a …
|
| 关 键 词： | 三乙酰基苯 三苯并咪唑盐 格林试剂 合成方法 |
| 收稿时间： | 2006-03-10 |
Novel Synthetic Method for Triacetylbenzene |
| |
| Bin ZHANG,Yong GAO,Jian Li LI,Zhen SHI. Novel Synthetic Method for Triacetylbenzene[J]. Chinese Chemical Letters, 2006, 17(9): 1165-1168 |
| |
| Authors: | Bin ZHANG Yong GAO Jian Li LI Zhen SHI |
| |
| Abstract: | Triacetylbenzene was prepared from tribenzimidazolium salt and Grignard reagent. The addition-hydrolysis reaction of tribenzimidazolium salt with Grignard reagent is reported and a novel method for preparation of triacetylbenzene is provided. |
| |
| Keywords: | Triacetylbenzene tribenzimidazolium salt Grignard reagent synthesis. |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
