Interpretation of the i.r. and Raman spectrum of acetonitrile solutions of electrolytes in the CN stretching region |
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| Affiliation: | 1. Department of Dental Technology and Materials Science, Central Taiwan University of Science and Technology, Taiwan, ROC;2. Institute of Biomedical Engineering and Materials Science, Central Taiwan University of Science and Technology, Taiwan, ROC;3. Department of Mechanical and Automation Engineering, Da-Yeh University, Taiwan, ROC;4. Department of Chemical and Materials Engineering, National University of Kaohsiung, Kaohsiung, Taiwan, ROC;1. Université Grenoble Alpes, Institut Néel, F-38042 Grenoble, France;2. CNRS, Institut Néel, F-38042 Grenoble, France;3. CNRS, CEMES (Centre d''Elaboration des Matériaux et d''Etudes Structurales), B.P. 94347, 29 rue Jeanne Marvig, F-31055 Toulouse, France;4. Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Bellaterra, 08193 Barcelona, Spain;1. Dept. Materials Sci. & Eng, Nat''l Dong Hwa Univ, Hualien, Taiwan, ROC;2. Dept. Materials & Optoelectronic Sci, Nat''l Sun Yat-sen Univ, Kaohsiung, Taiwan, ROC;3. Central Geo. Survey, P.O. Box 968, Taipei, Taiwan, ROC;4. Inst. Earth Sci., Academia Sinica, Taipei, Taiwan, ROC;5. Institute Geology and Mineralogy of SBRAS, 630090 Novosibirsk, Russia;6. Novosibirsk State University, 2 Pirogov Str, 630090 Novosibirsk, Russia |
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| Abstract: | The effects of the cation—molecule interaction on the i.r. and Raman intensity of the CN stretching band in hydrogen cyanide are investigated. It follows from the calculated data that the cation—molecule interaction increases about 10 times the i.r. intensity of the CN stretching band, while the corresponding Raman intensity is slightly decreased. The present theoretical data for HCN and HCN … Li+ are utilized for the interpretation of the observed spectroscopic regularities in the i.r. Raman spectra of acetonitrile solutions of electrolytes. |
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