Contribution à la connaissance des o-menthols et des o-menthones (carquéjanols et carquéjanones) - 1ère communication |
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Authors: | Maria-Giulia Ferretti-Alloise,Andr Jacot-Guillarmod,Yves-Ren Naves |
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Affiliation: | Maria-Giulia Ferretti-Alloise,André Jacot-Guillarmod,Yves-René Naves |
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Abstract: | The mixture of carquejanols obtained from carquejol of carqueja oil has been converted in ketones. The alkohols obtained respectively by hydrogenation on Pt(O2), by lithium-aluminiumhydride reduction and by Meerwein-Ponndorf-Verley reaction have been separated by vapour phase chromatography. The ketones obtained from the Beckmann oxidation of the alkohols has been identified as carquejanone and isocarquejanone by application of the Auwers-Skita rule. |
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