Co(salen) catalyzed oxidation of oximes with t-butyl hydroperoxide |
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| Authors: | A. Nishinaga S. Yamazaki T. Miwa T. Matsuura |
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| Affiliation: | (1) Department of Synthetic Chemistry, Kyoto University, Yoshida, Kyoto, Japan;(2) Present address: Department of Applied Chemistry, Osaka Institute of Technology, Ohmiya 5, Asahi-ku, 535 Osaka, Japan |
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| Abstract: | Co(salen) catalyzed the oxidation of oximes with t-butyl hydroperoxide to give the parent carbonyl compounds, providing a new convenient route to deoximation reaction. A plausible mechanism involves a substrate radical intermediate.
Co(     )              -   ,   .    .     . |
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