| 路易斯酸碱催化的外消旋体(动态)动力学拆分反应 |
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| 引用本文： | 张占金,毛金城,万伯顺,陈惠麟. 路易斯酸碱催化的外消旋体(动态)动力学拆分反应[J]. 化学进展, 2004, 16(4): 574-583 |
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| 作者姓名： | 张占金 毛金城 万伯顺 陈惠麟 |
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| 作者单位： | 渤海大学化学与食品科学学院,锦州,121000;中国科学院大连化学物理研究所,大连,116023;中国科学院大连化学物理研究所,大连,116023 |
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| 摘 要： | 外消旋体的(动态)动力学拆分反应是制备手性化合物的重要方法之一.反应可以通过酶催化或非酶催化的手段来实现,也可以通过两种方法的有机结合来进行.在非酶催化反应中,路易斯酸碱催化是比较常用的方法,它们被广泛地用于多种外消旋体的(动态)动力学拆分反应中,目前在该领域取得了很大的进展.本文讨论了路易斯酸及路易斯碱催化体系在外消旋体(动态)动力学拆分反应中应用的最新进展.
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| 关 键 词： | 路易斯酸碱 外消旋体 (动态)动力学拆分 非酶催化 |
| 文章编号： | 1005-281X(2004)04-0574-10 |
| 收稿时间： | 2003-03-01 |
| 修稿时间： | 2003-03-01 |
(Dynamic) Kinetic Resolution Reactions of Racemes Catalyzed by Lewis Acid and Base Catalysts |
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| Zhang Zhanjin,Mao Jincheng,Wan Boshun,Chen Huilin. (Dynamic) Kinetic Resolution Reactions of Racemes Catalyzed by Lewis Acid and Base Catalysts[J]. Progress in Chemistry, 2004, 16(4): 574-583 |
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| Authors: | Zhang Zhanjin Mao Jincheng Wan Boshun Chen Huilin |
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| Affiliation: | (1.College of Chemistry and Food Science, Bohai University, Jinzhou 121000; 2.Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023) |
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| Abstract: | The (dynamic) kinetic resolution of raceme is one of the important ways in the synthesis of chiral compounds. The reaction can be realized by enzymatic or non-enzymatic catalysis or by combination of two methods. The catalytic systems of Lewis acid and base are useful ways in the non-enzymatic catalysis. They were widely used to different kinds of (dynamic) kinetic resolution reactions. At present, mighty advances have been made in the field.Recent progress in the applications of non-enzymatic system about Lewis acid and base to (dynamic)kinetic resolution reactions of racemes is reviewed. |
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| Keywords: | Lewis acid and base raceme (dynamic)kinetic resolution non-enzymatic catalysis |
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