Catalytic acylation of amines with aldehydes or aldoximes |
| |
| Authors: | Allen C Liana Davulcu Simge Williams Jonathan M J |
| |
| Institution: | Department of Chemistry, University of Bath, Claverton Down, Bath, U.K., BA2 7AY. |
| |
| Abstract: | The simple nickel salt NiCl(2)·6H(2)O catalyzes the coupling of aldoximes with amines to give secondary or tertiary amide products. The aldoxime can be prepared in situ from the corresponding aldehyde. The use of (18)O-labeled oximes has allowed insight into the mechanism of this reaction. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
