From conventional to microphotochemistry: photodecarboxylation reactions involving phthalimides |
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Authors: | Shvydkiv Oksana Gallagher Sonia Nolan Kieran Oelgemöller Michael |
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Institution: | Dublin City University, School of Chemical Sciences, Dublin 9, Ireland. |
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Abstract: | A series of acetone-sensitized photodecarboxylation reactions involving phthalimides have been investigated using conventional and microphotochemistry. Both, intra- and intermolecular transformations were compared. In all cases examined, the reactions performed in microreactors were superior in terms of conversions or isolated yields. These findings unambiguously prove the advantage of microphotochemistry over conventional photochemical techniques. |
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