Peripheral and non-peripheral-designed multifunctional phthalocyanines; synthesis, electrochemistry, spectroelectrochemistry and metal ion binding studies |
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Authors: | Arma?an GünselMehmet Kandaz At?f KocaBekir Salih |
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Institution: | a Department of Chemistry, Sakarya University, 54100 Esentepe, Sakarya, Turkey b Chemical Engineering Department, Engineering Faculty, Marmara University, 34722 Göztepe, Istanbul, Turkey c Hacettepe University, Department of Chemistry, Faculty of Science, Beytepe Campus, Ankara 06532, Turkey |
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Abstract: | A novel type of ionophore ligands, 3′-(2,3-dihydroxypropylthio)-phthalonitrile and 4′(2,3-dihydroxypropylthio)-phthalonitrile, and their α- and β-tetrasubstituted metallo phthalocyanines, (MPc), (M = ZnII, CoII, MnIIICl, FeIIIAc, CuII) have been prepared and fully characterized by elemental analysis, FT-IR, 1H and 13C NMR, and MS (ESI and Maldi-TOF). The complexes are soluble in both polar and non-polar solvents, such as MeOH and EtOH, THF, CHCl3 and CH2Cl2. The spectroscopic properties of the complexes are affected strongly by the electron-donating sulfanyl units on the periphery of the phthalocyanines. The cation binding properties of the complexes, for example using AgI and PdII, were evaluated by UV-Vis spectroscopy and the results show the formation of polynuclear phthalocyanine complexes. Functional donors on the periphery of the zinc and copper complexes coordinate to AgI and PdII to give ca. a 2:1 metal-phthalocyanine complex binding ratio for the concentration of 2.5 × 10−5 M (Pc) and 1.0 × 10−3 M (Metal ions). Voltammetric and in-situ spectroelectrochemical studies were performed to characterize the redox behavior of the complexes. An in-situ electrocolorimetric method was applied to investigate the colors of the electro-generated anionic and cationic forms of the complexes. |
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Keywords: | Phthalocyanines Aggregation Metal sensor Electrochemistry In-situ spectroelectrochemistry In-situ electrocolorimetry |
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