Synthesis and characterization of a new organo-soluble metal-free and metallophthalocyanines bearing flexible moieties |
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Authors: | Asiye NasHalit Kantekin |
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Affiliation: | Department of Chemistry, Karadeniz Technical University, 61080 Trabzon, Turkey |
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Abstract: | This paper describes a new symmetric metal-free phthalocyanine and its transition metal complexes which were prepared by a condensation of 1,2-dihydroacenaphthylen-1-ol 1 and 4-nitro phthalonitrile 2 with Co(II), Ni(II), Cu(II), and Zn(II) salts in 2-(dimethylamino)ethanol, respectively. The novel phthalocyanines bearing oxygen donor atoms on peripheral position have been characterized by IR, UV-Vis, 1H NMR, 13C NMR, Mass spectra and elemental analysis. The thermal behaviours of 4-8 were investigated by TG/DTA. |
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Keywords: | 1,2-Dihydroacenaphthylen-1-ol Metallophthalocyanine Microwave-assisted 4-Nitrophthalonitrile Thermal stability |
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