Dioxo- and oxovanadium(V) complexes of biomimetic hydrazone ONO and NNS donor ligands: Synthesis, crystal structure and catalytic reactivity |
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Authors: | Hassan Hosseini Monfared Samaneh KheirabadiNasim Asghari Lalami Peter Mayer |
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Affiliation: | a Department of Chemistry, Zanjan University, 45195-313 Zanjan, Iran b Fakultät für Chemie und Pharmazie, Ludwig-Maximilians-Universität, München, Butenandtstr. 5-13, Haus D, D-81377 München, Germany |
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Abstract: | Oxo- and dioxo-vanadium(V) complexes of hydrazone ONO donor ligands with the formula [VVO(μ2-OCH3)(L1)]2 (1) and [VVO2(L2)]·H2O (2) were synthesized by the reaction of [VO(acac)2] with proton-transfer complexes of benzenetricarboxylic acid/benzoylhydrazide and benzenetricarboxylic acid/isonicotinohydrazide, respectively (H2L1 = monocondensation of benzoylhydrazide and acetylacetone, H2L2 = monocondensation of isonicotinohydrazide and acetylacetone). Dioxo complex of V(V), [VO2(L3)] (3), was synthesized by the reaction of equimolar amounts of VO(acac)2, 2-acetylpyridine and thiosemicarbazide (H2L3 = hydrazone Schiff base of acetylpyridine and thiosemicarbazide and Hacac = acetylacetone). They were characterized by FT-IR, UV-Vis and NMR spectroscopic methods. The crystal structures of 1 and 2 were determined by X-ray analyses. The 1H NMR spectrum of the complex 1 in CDCl3 solution indicated that this dimeric complex is converted appreciably into its respective monomeric form. The catalytic potential of the complexes has been tested for the oxidation of alkene, alkane and aromatic hydrocarbons using H2O2 as the terminal oxidant. Good to excellent conversions have been obtained for the oxidation of most of the hydrocarbons. |
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Keywords: | Methoxy-bridged vanadium complex Hydrazone complexes Crystal structure Catalytic activity Proton-transfer complex |
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