Alkyldiamine bis(selenocyanato)cadmium(II) complexes: Synthesis, Cd, Se, N and C NMR spectroscopy and X-ray structure of a 2D metal-organic framework |
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| Authors: | Mohammed FettouhiBassem A. Al-Maythalony M. Nasiruzzaman ShaikhMohammed I.M. Wazeer Anvarhusein A. Isab |
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| Affiliation: | Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia |
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| Abstract: | Complexes of cadmium(II)-selenocyanate with several alkyldiamine ligands have been synthesized and characterized by IR, 113Cd, 77Se, 15N and 13C NMR spectroscopy. The X-ray structure of the complex [Cd(SeCN)2-en] reveals two non-equivalent metal ion centers, both with a distorted octahedral geometry. The combined bridging modes of selenocyanate and ethylenediamine with the blocking mode of a chelating ethylenediamine generate a 2D metal-organic framework. |
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| Keywords: | Cadmium(II) complexes Selenocyanate Ethylenediamine Solid state NMR 113Cd NMR X-ray structure |
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