Synthesis and characterization of new soluble fluorinated seco-porphyrazines |
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Authors: | Murat AltunkayaErgün Gonca |
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Institution: | Department of Chemistry, Fatih University, TR34500 B. Cekmece, Istanbul, Turkey |
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Abstract: | Magnesium porphyrazinate substituted with eight 3,5-bis(trifluoromethyl)phenyl groups on the peripheral positions has been synthesized by the cyclotetramerization of 3,4-3,5-bis(trifluoromethyl)phenyl]pyrroline-2,5-diimine in the presence of magnesium butanolate. Acid-mediated demetallation of the magnesium porphyrazine resulted in peripheral oxidation of one pyrrole ring to reveal the seco-porphyrazine, octakis3,5-bis(trifluoromethyl)phenyl]-2-seco-porphyrazine-2,3-dione. Further reaction of this product with copper (II) acetate, zinc (II) acetate and cobalt (II) acetate has led to the metallo-derivatives, {octakis3,5-bis(trifluoromethyl)phenyl]-2-seco-2,3-dioxoporphyrazinato} M(II) M = Cu(II), Zn(II), Co(II)]. These new soluble complexes were characterized by elemental analysis, together with FT-IR, 1H NMR, 13C NMR, 19F NMR, UV-Vis and mass spectral data. |
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Keywords: | 3 5-Bis(trifluoromethyl)phenyl Seco-porphyrazine Pyrroline 19F NMR spectroscopy Magnesium Copper |
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