Copper(II) complexes of bis(pyrazol-1-yl)methane - Synthesis, spectroscopic characterization, X-ray structure and DFT calculations |
| |
| Authors: | B. Machura J.G. Ma?eckiA. ?witlicka I. NawrotR. Kruszynski |
| |
| Affiliation: | a Department of Crystallography, Institute of Chemistry, University of Silesia, 9th Szkolna St., 40-006 Katowice, Poland
b Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Lodz University of Technology,116 ?eromski St., 90-924 ?ód?, Poland |
| |
| Abstract: | Two novel copper(II) complexes incorporating bis(pyrazol-1-yl)methane ligand (bpzm) have been synthesized. The compounds [CuCl(bpzm)2(H2O)]Cl·H2O (1) and [Cu(N3)2(bpzm)]n (2) have been studied by IR, UV-Vis spectroscopy and X-ray crystallography. The experimental studies on the compounds 1 and 2 have been accompanied computationally by the density functional theory (DFT) calculations. |
| |
| Keywords: | Copper(II) Bis(pyrazol-1-yl)methane Azide ion X-ray structure DFT calculations |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
