Copper(II) complexes of bis(pyrazol-1-yl)methane - Synthesis, spectroscopic characterization, X-ray structure and DFT calculations |
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| Authors: | B Machura JG Ma?eckiA ?witlicka I NawrotR Kruszynski |
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| Institution: | a Department of Crystallography, Institute of Chemistry, University of Silesia, 9th Szkolna St., 40-006 Katowice, Poland
b Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Lodz University of Technology,116 ?eromski St., 90-924 ?ód?, Poland |
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| Abstract: | Two novel copper(II) complexes incorporating bis(pyrazol-1-yl)methane ligand (bpzm) have been synthesized. The compounds CuCl(bpzm)2(H2O)]Cl·H2O (1) and Cu(N3)2(bpzm)]n (2) have been studied by IR, UV-Vis spectroscopy and X-ray crystallography. The experimental studies on the compounds 1 and 2 have been accompanied computationally by the density functional theory (DFT) calculations. |
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| Keywords: | Copper(II) Bis(pyrazol-1-yl)methane Azide ion X-ray structure DFT calculations |
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