Promotion of acetophenone formation from methyl(phenyl)rhodium carbonyl complexes by organic halides |
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| Authors: | Glenn J. Sunley Francesco P. Fanizzi Isabel M. Saez Peter M. Maitlis |
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| Affiliation: | Department of Chemistry, The University, Sheffield S3 7HF Great Britain |
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| Abstract: | [C5Me5RhPh(CO)CH3] reacted thermally to give acetophenone (27%) and toluene (9%); acetophenone formation was substantially increased in the presence of halobenzenes PhX (the order of effectiveness being X = I> Br> Cl) or methyl iodide, but 1-electron oxidisers promoted C---C coupling (toluene formation). |
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