| 含吡唑杂环二酰胺类化合物的合成与杀虫活性研究 |
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| 引用本文： | 葛前建,陈列忠,杜晓华.含吡唑杂环二酰胺类化合物的合成与杀虫活性研究[J].有机化学,2011,31(9). |
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| 作者姓名： | 葛前建 陈列忠 杜晓华 |
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| 作者单位： | 1. 浙江工业大学催化加氢研究中心 杭州310014
2. 浙江省农科院 杭州310021 |
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| 基金项目： | 浙江省重大科技专项(No.2008C01061-2)资助项目 |
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| 摘 要： | 通过活性亚结构拼接,合成16个含吡唑杂环的新型二酰胺类化合物,其结构通过了IR,1H NMR和HRMS的表征,其中目标化合物3h的结构经X单晶衍射进一步确认.初步生测结果表明在500 mg/L浓度下,部分化合物对粘虫和苜蓿蚜有致死活性；在100 mg/L浓度下部分化合物对茶尺蠖幼虫具有致死活性,其中毒症状表现为拒食.
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| 关 键 词： | 活性亚结构 双酰胺化合物 鱼尼汀受体激活剂 合成 杀虫活性 |
Synthesis and Insecticidal Activities of Pyrazole-heterocyclic Diamides |
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| Ge Qianjian,Chen Liezhong,Du Xiaohua.Synthesis and Insecticidal Activities of Pyrazole-heterocyclic Diamides[J].Chinese Journal of Organic Chemistry,2011,31(9). |
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| Authors: | Ge Qianjian Chen Liezhong Du Xiaohua |
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| Institution: | Ge,Qianjiana Chen,Liezhongb Du,Xiaohua*,a(a Catalytic Hydrogenation Research Center,Zhejiang University of Technology,Hangzhou 310014)(b Zhejiang Academy of Agricultural Sciences,Hangzhou 310021) |
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| Abstract: | 16 novel pyrazole-heterocyclic diamides were synthesized according to the principle of combination of bioactive substructures,and their structures were characterized by IR,1H NMR and HRMS techniques.The crystal structure of 3h was determined by X-ray diffraction analysis.Preliminary bioassays showed that some compounds had lethal activities against Mythimna sepatara and Aphis medicaginis at the dosage of 500 mg/L;some of the compounds had lethal activities against the larvae of Ectropis oblique hypulina Weh... |
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| Keywords: | bioactive substructure diamides ryanodine receptor activator synthesis insecticidal activity |
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