| 轮烷类化合物的合成方法研究进展 |
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| 引用本文： | 纪奉元,朱亮亮.轮烷类化合物的合成方法研究进展[J].有机化学,2011,31(7). |
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| 作者姓名： | 纪奉元 朱亮亮 |
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| 作者单位： | 华东理工大学精细化工研究所 结构可控先进功能材料及其制备教育部重点实验室 上海 200237 |
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| 摘 要： | 轮烷类互锁分子因其多样的结构和性质,多年来一直是超分子化学领域的一个热点.综述了近年来轮烷类化合物的合成及制备方法,包括用传统的模板法(引入氢键、疏水作用、静电效应、配位和离子诱导等超分子作用)制备轮烷类化合物.除此之外,还介绍了利用“Click”化学、“穿线-收缩”、“穿线-膨胀”、自排序组织和自由基识别等新的合成手段来制备这类化合物.
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| 关 键 词： | 超分子 轮烷 模板法 |
Progress on Synthesis of Rotaxane Analogues |
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| Ji Fengyuan,Zhu Liangliang.Progress on Synthesis of Rotaxane Analogues[J].Chinese Journal of Organic Chemistry,2011,31(7). |
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| Authors: | Ji Fengyuan Zhu Liangliang |
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| Institution: | Ji,Fengyuan Zhu,Liangliang(Key Laboratory for Advanced Materials and Institute of Fine Chemicals,East China University of Science & Technology,Shanghai 200237) |
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| Abstract: | Rotaxane-based interlocked molecular system has become a hot issue in supramolecular chemis-try for years,owing to its various structural architectures and performances.This tutorial review mainly fo-cuses on the synthetic strategies of the rotaxane analogues in recent years.The traditional template-directed strategies of rotaxane preparation including the employment of the supramolecular interaction such as hy-drogen bonding,hydrophobic effect,electrostatic interaction,coordination and ionic template are r... |
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| Keywords: | supramolecular rotaxane template-directed strategies |
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