First regioselective cyclometalation reactions of cobalt in arylketones: C-H versus C-F activation |
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| Authors: | Camadanli Sebnem Beck Robert Flörke Ulrich Klein Hans-Friedrich |
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| Institution: | Eduard-Zintl Institut, Technische Universit?t Darmstadt, Petersenstrasse 18, 64287, Darmstadt, Germany. sebnem.camadanli@iom-leipzig.de |
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| Abstract: | Phenyl ketones react smoothly under mild conditions with low valent cobalt(i) adducts to form new and stable five-membered cobaltacycles via C-H and C-F activation. |
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