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Large melting-point hysteresis of Ge nanocrystals embedded in SiO2
Authors:Xu Q  Sharp I D  Yuan C W  Yi D O  Liao C Y  Glaeser A M  Minor A M  Beeman J W  Ridgway M C  Kluth P  Ager J W  Chrzan D C  Haller E E
Affiliation:Department of Materials Science and Engineering, University of California, Berkeley, California 94720, USA.
Abstract:The melting behavior of Ge nanocrystals embedded within SiO2 is evaluated using in situ transmission electron microscopy. The observed melting-point hysteresis is large (+/-17%) and nearly symmetric about the bulk melting point. This hysteresis is modeled successfully using classical nucleation theory without the need to invoke epitaxy.
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