Synthesis and structure of a hexacoordinate carbon compound |
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| Authors: | Yamaguchi Torahiko Yamamoto Yohsuke Kinoshita Daisuke Akiba Kin-ya Zhang Yun Reed Christopher A Hashizume Daisuke Iwasaki Fujiko |
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| Affiliation: | Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan. |
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| Abstract: | In an exploration of six coordination and hypervalence in carbon compounds, steric constraints have been employed to bring four ether O atoms in close proximity to an allenic carbon atom. The dimethylated dication 2 is confirmed to have hexacoordinate carbon by experimental charge density analysis and DFT calculations and is arguably hypervalent. |
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