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Optical activity of dielectric superlattices with defects
Authors:V. V. Rumyantsev  S. A. Fedorov  K. V. Gumennik
Affiliation:(1) Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences, 450054 Ufa, Russia;(2) 2 N. A. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
Abstract:Natural optical activity of a nonideal 1D multilayer system is considered phenomenologically and the concentration dependence of its specific rotation angle is simulated numerically. As a model system, the two-sublattice SiO2 LC structure was chosen. Specific gyrotropy features caused by the corresponding disordering types of the studied systems were revealed. Based on the developed phenomenological theory, the frequency dependence of the specific rotation angle of the polarization plane of linearly polarized light was studied for the case of a molecular-crystal multilayer system whose layers contain pointlike defects. This creates additional possibilities for simulating optically active multilayer composite materials.
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