Electrocarboxylation of 1,4-dibromobut-2-ene in a CO2-DMF liquid mixture |
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| Authors: | V A Grinberg T A Koch V M Mazin E I Mysov S R Sterlin |
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| Institution: | (1) A. N. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117071 Moscow, Russian Federation;(2) Central Research and Development E. I. Du Pont de Nemours and Company, Inc., Experimental Station, P.O. Box 80262, 19880-0262 Wilmington, DE, USA |
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| Abstract: | The possibility of synthesizing dihydromuconic acid by cathodic carboxylation of 1,4-dibromobut-2-ene in the liquid CO2-aprotic solvent system was investigated. The low yield of dihydromuconic acid in this reaction was explained by the competing
reductive debromodimerization and oligomerization of 1,4-dibromobut-2-ene, which lead to the predominant formation of 1,8-dibromo-2,6-octadiene
and polymeric products.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1637–1641, September, 1997. |
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| Keywords: | 1 4-dibromobut-2-ene electrochemical carboxylation |
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