| 基于N,O-双异丁烯酰乙醇胺为交联功能单体的苯磺隆分子印迹聚合物膜的制备及其性能研究 |
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| 引用本文： | 柳絮飞,周杰,陈长宝. 基于N,O-双异丁烯酰乙醇胺为交联功能单体的苯磺隆分子印迹聚合物膜的制备及其性能研究[J]. 高等学校化学学报, 2009, 30(9): 1717-1723 |
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| 作者姓名： | 柳絮飞 周杰 陈长宝 |
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| 作者单位： | 山东农业大学化学与材料科学学院,泰安,271018;山东农业大学化学与材料科学学院,泰安,271018;山东农业大学化学与材料科学学院,泰安,271018 |
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| 基金项目： | 国家“八六三”计划专题课题基金(批准号:2007AA10Z432)资助 |
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| 摘 要： | 以苯磺隆为模板分子, N,O-双异丁烯酰乙醇胺为交联功能单体, 在尼龙-6膜上通过紫外光照引发合成了分子印迹聚合物膜, 并用扫描电镜对其表面形态进行了表征. 用紫外分光光谱法研究了模板分子与交联功能单体之间的相互作用. 印迹因子的测定和底物竞争渗透实验结果表明, 分子印迹聚合物膜对模板分子苯磺隆具有较高的选择性, 而非分子印迹聚合物膜没有选择性.
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| 关 键 词： | 分子印迹聚合物膜 苯磺隆 N O-双异丁烯酰乙醇胺 |
| 收稿时间： | 2009-03-10 |
Preparation of a N,O-Bismethacryloyl Ethanolamine-based Tribenuron-methly Imprinted Polymeric Membrane over a Nylon-6 Support and Its Transport Selectivity |
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| LIU Xu-Fei,ZHOU Jie,CHEN Chang-Bao. Preparation of a N,O-Bismethacryloyl Ethanolamine-based Tribenuron-methly Imprinted Polymeric Membrane over a Nylon-6 Support and Its Transport Selectivity[J]. Chemical Research In Chinese Universities, 2009, 30(9): 1717-1723 |
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| Authors: | LIU Xu-Fei ZHOU Jie CHEN Chang-Bao |
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| Affiliation: | College of Chemistry and Material Science, Shandong Agricultural University, Taian 271018, China |
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| Abstract: | Using tribenuron-methly as a template molecule and N,O-bismethacryloyl ethanolamine as a functional linked monomer,a molecularly imprinted membrane over a Nylon-6 support was prepared by UV irradiation.The surface of the molecularly imprinted membrane was studied by scanning electron microscopy.The interaction between the template molecule and the functional linked monomer was evaluated by UV spectrophotometric method.The permeation experiments throughout the imprinted membrane and non-imprinted one were ca... |
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| Keywords: | Molecularly imprinted polymer membrane Tribenuron-methly N O-Bismethacryloyl ethanolamine |
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