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Incremental expansion of the classical partition functions
Affiliation:1. Theoretische Chemie, Physikalisch–Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 229, D-69120 Heidelberg, Germany;2. Department of Physics, University of Haifa at Oranim, Tivon 36006, Israel;1. Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80303, USA;2. Dow Corning Europe SA, Rue Jules Bordet, Park Industrial – Zone C, B-7180 Seneffe, Belgium;1. S. N. Bose National Centre for Basic Sciences, JD Block, Sector III, Salt Lake, Kolkata 700106, India;2. Indian Institute of Technology Bhubaneswar, Bhubaneswar 751013, India;3. Indian Institute of Science Education and Research Kolkata, Mohanpur 741246, India;1. Dipartimento di Ingegneria dell’Energia Elettrica e dell’Informazione “Guglielmo Marconi” - DEI, Università di Bologna, I-40136 - Bologna, Italy;2. Quantum Technology Lab, Dipartimento di Fisica, Università degli Studi di Milano, I-20133 - Milano, Italy;3. Dipartimento di Scienze Fisiche, Informatiche e Matematiche — FIM, Università di Modena e Reggio Emilia, I-41125 - Modena, Italy;4. Centro S3, CNR-Istituto di Nanoscienze, I-41125 - Modena, Italy
Abstract:The incremental expansion of the canonical partition function of a classical many-particle system is obtained. The incremental expansion coefficients are calculated for the case of a pair interaction potential. The results are used to derive the incremental expansion of the system free energy.
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