Two new coordination host frameworks for the inclusion of 4-amino-benzophenone guest molecules |
| |
| Affiliation: | 1. Power Mechanical Engineering, National Tsing Hua Univ., Hsinchu, Taiwan;2. National Applied Research Laboratories, National Center for High-performance Computing, Hsinchu, Taiwan;3. Institute of NanoEngineering and MicroSystems, National Tsing Hua Univ., Hsinchu, Taiwan;1. State Key Laboratory of Mechanical System and Vibration, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;2. State Key Laboratory of Ocean Engineering, School of Naval Architecture, Ocean & Civil Engineering, Shanghai Jiao Tong University, Shanghai 200240, China |
| |
| Abstract: | The synthesis and structural characterization of novel organometallic coordination polymers are reported. The reaction of Cd(NO3)2 and 4,4′-bipy in CH3OH/H2O gave a 2D coordination network formulated as {[Cd(4,4′-bpy)2·(H2O)2](NO3)2·4H2O}10, which was used to capture an organic guest species (4-amino-benezopheone, C13H11NO (3)) to obtain {[Cd(4,4′-bpy)2(NO3)(H2O)]·NO3·(C13H11NO)2} (1). Using L (L=4,4′-trimethylenedipyridine) instead of 4,4′-bipy, {[Cd(L)2(H2O)2]·2H2O·2NO3·C13H11NO} (2) was synthesized, which has an interesting configuration. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
