Preparation and properties of new ferrocenyl heterobimetallic complexes with counterion dependent NLO responses |
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| Institution: | 1. Departamento de Qu??mica Inorgánica y Orgánica, Universitat Jaume I, E-12080 Castellon, Spain;2. Departamento de Ciencias Experimentales, Universitat Jaume I, E-12080 Castellon, Spain;3. Laboratory of Chemical and Biological Dynamics, Centre for Research on Molecular Electronics and Photonics, University of Leuven, Celestijnenlaan 200D, B-3001 Leuven, Belgium;1. The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials (State Key Laboratory Cultivation Base), College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241002, China;2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou 350002, China;1. Instituto Nacional de Astrofísica Óptica y Electrónica, Calle Luis Enrique Erro, Santa Maria Tonantzintla Puebla, C.P. 72840, Mexico;2. Universidad Popular Autónoma del Estado de Puebla, calle 21 sur #1103 Barrio santiago, Puebla, C.P. 72410, Mexico;1. Department of Chemistry, Brock University, St. Catharines, Ontario L2S 3A1, Canada;2. Department of Chemistry, University of Cyprus, 1678 Nicosia, Cyprus;3. Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, USA;4. Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA;1. University of Science and Technology Beijing, Beijing, 100083, PR China;2. Division of Material Engineering, China Academy of Space Technology, Beijing, 100094, PR China |
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| Abstract: | New ferrocenyl-based bimetallic cationic compounds of the type of (E)-CpFe(η5-C5H4)(CHCH)(C6H4)CNRuCp(PPh3)2]X (X=PF6, BF4) and of (E)-CpFe(η5-C5H4)(CHCH)(C6H4)CNFeCp(CO)2]PF6 have been obtained and characterized. The crystal structure of (E)-CpFe(η5-C5H4)(CHCH)(C6H4)CNRuCp(PPh3)2]BF4 has been established by means of X-ray diffractometry. The NLO responses of the compounds have been studied by the hyper-Rayleigh scattering technique and the hyperpolarizability is found to be dependent on the nature of the counterion. |
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