Cu+ and Pt2+ complexes with a p-tert-butylcalix[4]arene fitted with two phosphine pendant arms |
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| Institution: | 1. Ricoh Co., Ltd, Japan;2. Department of Mechanical Engineering, Yokohama National University, Japan;1. Division of Science and Technology, Beijing Normal University-Hong Kong Baptist University United International College, Zhuhai Guangdong, PR China;2. Department of Electronic Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong;3. College of Science and Technology, Dongguan University of Technology, Dongguan, Guangdong, PR China;1. State key lab of powder metallurgy, Central South University, Changsha 410083, China;2. Department of Inorganic Materials, School of Resources Processing and Bioengineering, Central South University, Changsha 410083, China;1. School of Mechanical and Nuclear Engineering, Ulsan National Institute of Science and Technology (UNIST), UNIST-gil 50, Banyeon-ri, Eonyang-eup, Ulju-gun, Ulsan 689-798, Republic of Korea;2. School of Mechanical Engineering, Pusan National University (PNU), Busandaehak-ro 63, Beon-gil, Geumjeong-gu, Busan 609-735, Republic of Korea;1. MonashHeart, Monash Health, Clayton, Victoria, Australia;2. Monash Cardiovascular Research Centre, Monash University, Clayton, Victoria, Australia |
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| Abstract: | Reaction of 5,11,17,23-tetra-tert-butyl-25,27-dihydroxy-26,28-bis{N-(2-diphenyl phosphino)phenyl}carboxyamidemethoxy]calix4]arene with Cu(CH3CN)4]ClO4 and Pt(COD)Cl2 gave two new complexes (1 and 2, respectively). Their structures were determined by X-ray analysis. Complex 1 has two seven-membered metallo-cycles and complex 2 has one five-membered metallo-cycle. |
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