Functionally Substituted Amides and Esters of 3,4,4-Trichloro-3-butenoic Acid |
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| Authors: | Petkevich S. K. Dikusar E. A. Potkin V. I. Kaberdin R. V. Moiseichuk K. L. Yuvchenko A. P. Kurman P. V. |
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| Affiliation: | (1) Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus |
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| Abstract: | Substituted amides and esters of 3,4,4-trichloro-3-butenoic acid were prepared by reactions of its chloride with appropriate amines and alcohols. Treatment of 3,4,4-trichloro-3-butenomorpholide and tert-butyl 3,4,4-trichloro-3-butenoate results in nucleophilic substitution of the internal chlorine atom with the morpholine residue, accompanied by prototropic allyl rearrangement. |
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