| Synthesis and Structural Characterization of the Complex 〔Et_4N〕_2〔Ni_2(C_2S_4)(C_3S_5)_2〕 |
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| 作者姓名： | SHENG Tian Lu\ WU Xin Tao * WANG Quan Ming LIN Ping |
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| 作者单位： | State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter，the Chinese Academy of Sciences，Fuzhou，Fujian 350002 |
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| 摘 要： | １ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｃｈｅｍｉｓｔｒｙｏｆｃｏｍｐｏｕｎｄｓｗｉｔｈｄｍｉｔ（ｄｍｉｔ＝１，３ ｄｉｔｈｉｏｌｅ ２ ｔｈｉｏｎｅ ４，５ ｄｉｔｈｉｏｌａｔｅ）ｈａｓａｔｒａｃｔｅｄｃｏｎｓｉｄｅｒａｂｌｅａｔｅｎｔｉｏｎｒｅｃｅｎｔｌ...
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Synthesis and Structural Characterization of the Complex[Et4N]2[Ni2(C2S4)(C3S5)2] |
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| SHENG Tian,Lu\ WU Xin,Tao,*,WANG Quan,Ming,LIN Ping.Synthesis and Structural Characterization of the Complex[Et4N]2[Ni2(C2S4)(C3S5)2][J].Chinese Journal of Structural Chemistry,1999,18(1). |
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| Authors: | SHENG Tian-Lu WU Xin-Tao WANG Quan-Ming LIN Ping |
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| Abstract: | The heteroleptic dmit complex Et4N]2Ni2(C2S4)(C3S5)2] has been prepared by the reaction of NiCl2.H2O with Na2dmit, NaSC2H4OH in the MeOH solution. The compound has been characterized by X-ray diffraction study, IR and UV-Vis spectroscopy. Crystallographic data : space group: P21/n, a=11.843(2), b=11.079(1), c = 15.404(1)(), β=110.33(1)°, V = 1895.1()3, Z=2, Dc=1.62 g/cm3, μ=17.6 cm-1, F(000)=956, R=0.052, Rw=0.061. In the structure of the title complex, the tto (tto=tetrathioxalato) ligand in bridging form is chelated to two nickel atoms and dmit (dmit=1,3-dithiole-2-thione-4,5-dithiolate) ligands coordinated to nickel atoms. |
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| Keywords: | dinuclear nickel-dmit complex synthesis structure |
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