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Phase transition behavior for ZrW2−xMoxO8 compositions at elevated temperatures
Authors:Yongfang Shi  Xi Chen  Jingsa Han  Hui Ma  Xiaoxia Li  Xiaojing Yang  Xinhua Zhao  
Institution:aCollege of Chemistry and Analysis and Test Center, Beijing Normal University, Beijing 100875, PR China;bFujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China
Abstract:A systematical study on cubic ZrW2−xMoxO8 (x=0.73, 0.53, 0.33, 0.11) solid solutions reveals that their temperature-dependent phase transition behaviors are related to the Mo fraction x. A phase diagram of cubic ZrW2−xMoxO8 solid solutions has been drawn over a wide temperature range (298–1473 K) on the basis of the temperature-dependent phase transition behaviors observed.
Keywords:Materials science  Phase diagrams  Phase transformation  Negative thermal expansion  ZrW2O8
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