Nickel-catalyzed amination of aryl tosylates |
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Authors: | Gao Cai-Yan Yang Lian-Ming |
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Institution: | Beijing National Laboratory for Molecular Sciences, Laboratory of New Materials, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China. |
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Abstract: | The cross-coupling of aryl tosylates with amines and anilines was accomplished by using a Ni-based catalyst system from the combination of Ni(II)-(sigma-aryl) complexes/N-heterocyclic carbenes (NHCs). The feature, scope, and limitation of this reaction are disclosed. |
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