Anisotropy of light propagation in thin opal films

Thin opal films are prepared by crystallization in a moving meniscus, and their optical transmission spectra are recorded in polarized light and studied. It is shown that the anisotropy of light propagation in the films is unambiguously related to the photonic band structure of opal and depends on the angle of incidence, the orientation of the incidence plane with respect to the opal lattice, and the wavelength and polarization of the incident light. Azimuthal diagrams of transmitted polarized light are constructed in the range of photonic band gaps of three orders for oblique incidence of a light beam. The anisotropy is found to vary with the light wave-length independently in perpendicular polarizations. A model of the band structure of opal wherein opal is represented as an fcc lattice of close-packed spheres adequately describes the optical transmission of opal films only in the range of the first-order photonic band gap.