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Synthetic studies towards picrasane quassinoids
Authors:IS Marcos  N García  MJ Sexmero  FA Hernández  MA Escola  P Basabe  D Díez  JG Urones
Institution:Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad de Salamanca, Plaza de los Caidos 1-5, 37008 Salamanca, Spain
Abstract:An advanced intermediate 40 with the ABC ring of the picrasane quassinoid skeleton has been synthesised from ent-halimic acid. The bicyclic system of the starting material has been incorporated as the BC part of the ABC system. Until date, no diterpenes of the antipode series have been used in this kind of approach.
Keywords:Quassinoids  Picrasane  Triterpenes  ent-Halimic acid
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