| Unit Construction in the Formation of Metal Clusters──Investigation on the Metal Cluster CompoundsContaining Fe_2S_2(CO)_6-units |
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| 引用本文： | ZHUANG Bo-Tao ,PAN Bing-Hua ,HUANG Liang-Ren ,HE Ling-Jie,CHEN Peng-Cheng ,SUN Hao-Feng, PAN Guo-Hua(Fujian Institute of Research on the Structure of Matter,the Chinese Academy ofSciences,State Key Laboratory of Structural Chemistry,Fuzhou,350002,CHIN. Unit Construction in the Formation of Metal Clusters──Investigation on the Metal Cluster CompoundsContaining Fe_2S_2(CO)_6-units[J]. 结构化学, 1998, 0(1) |
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| 作者姓名： | ZHUANG Bo-Tao PAN Bing-Hua HUANG Liang-Ren HE Ling-Jie CHEN Peng-Cheng SUN Hao-Feng PAN Guo-Hua(Fujian Institute of Research on the Structure of Matter the Chinese Academy ofSciences State Key Laboratory of Structural Chemistry Fuzhou 350002 CHIN |
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| 作者单位： | Fujian Institute of Research on the Structure of Matter，the Chinese Academy ofSciences，State Key Laboratory of Structural Chemistry，Fuzhou，350002，CHIN |
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| 摘 要： | 1INTRODUCTIONThechemistryofMo--S,Fe--SandMo-Fe--Sclustercomplexeshasincreasinglyinterestedchemistsandbioinorganicchemistssincetheexistenceofmetal-sulfurbondinginmetalenzymes,especiallytheFe--Mo--Sclusterastheactivecenterinni-trogenase,wasdiscovered.Recently,aninterestingFe--SstructuralunitFeZSZ(CO),t'3,hasbeeningoodglancesofpeopleandthechemistryofthemetalclustercompoundscontainingFe,S,(CO),-unitshasbeenfocusedbygreatattentionbecausei)FeZSZ(CO)6isanironsourceforthesynthesisofMo-…
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Unit Construction in the Formation of Metal Clusters──Investigation on the Metal Cluster Compounds Containing Fe_2S_2(CO)_6-units |
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| ZHUANG Bo-Tao ,PAN Bing-Hua ,HUANG Liang-Ren ,HE Ling-Jie,CHEN Peng-Cheng ,SUN Hao-Feng, PAN Guo-Hua. Unit Construction in the Formation of Metal Clusters──Investigation on the Metal Cluster Compounds Containing Fe_2S_2(CO)_6-units[J]. Chinese Journal of Structural Chemistry, 1998, 0(1) |
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| Authors: | ZHUANG Bo-Tao PAN Bing-Hua HUANG Liang-Ren HE Ling-Jie CHEN Peng-Cheng SUN Hao-Feng PAN Guo-Hua |
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| Abstract: | The syntheses and structures of trinuclear Mo (W)-Fe-S cluster[MFe2S2(CO)8 (S,CNSEt2)]- (M=Mo, W), hexanuclear Fe-S cluster [Fe6S6-(CO)12]2- and undecanuclear Cu-Fe-S cluster [Cu5Fe6S6(CO)18(PPh3)2]-, containingFe2S2(CO)6-units bave been summarized and the important vestiges left in their struc-tures reflecting the formation processes of the clusters have been found and discussed.Further inspecting some other typical clusters a regular unit construction in the forma-tion of the metal cluster compounds containing Fe2S2(CO)6-units has been figured outand applied to speculate and predict several new cluster compounds containing Fe2S2(CO)6-units. |
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| Keywords: | unit construction Fe-Mo W Cu-S clusters synthesis structure and formation processes |
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