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Bench-Scale Testing of Zinc Ferrite Sorbent for Hot Gas Clean-up
作者姓名:Meisheng  Liang  Hongyan  Xu  Kechang  Xie
作者单位:Meisheng Liang,Hongyan Xu,Kechang Xie College of Environmental Science and Engineering,Taiyuan University of Technology,Taiyuan 030024,Shanxi,China; Key Laboratory for Coal Science and Technology of Shanxi Province and Ministry of Education,Taiyuan University of Technology,Taiyuan 030024,Shanxi,China
基金项目:科技部科研项目,国家自然科学基金
摘    要:Advanced integrated gasification combined cycle (IGCC) power generation systems require the development of high-temperature, regenerable desulfurization sorbents, which are capable of removing hydrogen sulfide from coal gasifier gas to very low levels. In this paper, zinc ferrites prepared by co-precipitation were identified as a novel coal gas desulfurization sorbent at high temperature. Preparation of zinc ferrite and effects of binders on pore volume, strength and desulfurization efficiency of zinc ferrite desulfurizer were studied. Moreover, the behavior of zinc ferrite sorbent during desulfurization and regeneration under the temperature range of 350-400℃are investigated. Effects of binders on the pore volume, mechanical strength and desulfurization efficiency of zinc ferrite sorbents indicated that the addition of kaolinite to zinc ferrite desulfurizer seems to be superior to other binders under the experimental conditions.

关 键 词:锌铁吸附剂  黏合剂  瓦斯  硫化作用
收稿时间:5 January 2007
修稿时间:2007-01-052007-03-13

Bench-Scale Testing of Zinc Ferrite Sorbent for Hot Gas Clean-up
Meisheng Liang Hongyan Xu Kechang Xie.Bench-Scale Testing of Zinc Ferrite Sorbent for Hot Gas Clean-up[J].Journal of Natural Gas Chemistry,2007,16(2):204-209.
Authors:Meisheng Liang  Hongyan Xu  Kechang Xie
Institution:aCollege of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;bKey Laboratory for Coal Science and Technology of Shanxi Province and Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China
Abstract:Advanced integrated gasification combined cycle (IGCC) power generation systems require the development of high-temperature, regenerable desulfurization sorbents, which are capable of removing hydrogen sulfide from coal gasifier gas to very low levels. In this paper, zinc ferrites prepared by co-precipitation were identified as a novel coal gas desulfurization sorbent at high temperature. Preparation of zinc ferrite and effects of binders on pore volume, strength and desulfurization efficiency of zinc ferrite desulfurizer were studied. Moreover, the behavior of zinc ferrite sorbent during desulfurization and regeneration under the temperature range of 350-400 ℃ are investigated. Effects of binders on the pore volume, mechanical strength and desulfurization efficiency of zinc ferrite sorbents indicated that the addition of kaolinite to zinc ferrite desulfurizer seems to be superior to other binders under the experimental conditions.
Keywords:zinc ferrite sorbent  binder  hot gas clean-up  sulfidation  regeneration
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