Aerobic Oxidation of Benzyl Alcohol Catalyzed by Cu-Mn Mixed Oxides and 2,2,6,6-Tetramethyl-piperidyl- 1-oxy1 |
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引用本文: | Yanchun Guo Junfeng Zhao Jinxia Xu Wei Wang Fengshou Tian Guanyu Yang Maoping Song. Aerobic Oxidation of Benzyl Alcohol Catalyzed by Cu-Mn Mixed Oxides and 2,2,6,6-Tetramethyl-piperidyl- 1-oxy1[J]. 天然气化学杂志, 2007, 16(2): 210-212 |
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作者姓名: | Yanchun Guo Junfeng Zhao Jinxia Xu Wei Wang Fengshou Tian Guanyu Yang Maoping Song |
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作者单位: | [1]Department of Chemistry, Zhengzhou University, Zhengzhou 550052, Henan, China [2]Department of Environmental Engineering, Zhengzhou Economic Management Institute, Zhengzhou 551191, Henan, China |
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基金项目: | Fundation items: the National Natural Science Foundation of China (No.20572102) |
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摘 要: |
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关 键 词: | 苯甲醇 催化作用 氧化物 需氧反应 |
修稿时间: | 2006-12-052007-01-15 |
Aerobic Oxidation of Benzyl Alcohol Catalyzed by Cu-Mn Mixed Oxides and 2,2,6,6-Tetramethyl-piperidyl- 1-oxy1 |
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Abstract: | Heterogeneous Cu-Mn mixed oxides can mediate TEMPO-catalyzed selective oxidation of benzyl alcohol by molecular oxygen under neutral condition, and is recyclable. In the case of the molar ratio of Cu and Mn over 1, the highly-dispersed CuO inside the Cu-Mn mixed oxides is responsible for the good performances in catalytic oxidation. |
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Keywords: | Cu-Mn oxides 2,2,6,6-tetramethyl-piperidyl-l-oxyl aerobic oxidation benzyl alcohol |
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