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Aerobic Oxidation of Benzyl Alcohol Catalyzed by Cu-Mn Mixed Oxides and 2,2,6,6-Tetramethyl-piperidyl- 1-oxy1
引用本文:Yanchun Guo Junfeng Zhao Jinxia Xu Wei Wang Fengshou Tian Guanyu Yang Maoping Song. Aerobic Oxidation of Benzyl Alcohol Catalyzed by Cu-Mn Mixed Oxides and 2,2,6,6-Tetramethyl-piperidyl- 1-oxy1[J]. 天然气化学杂志, 2007, 16(2): 210-212
作者姓名:Yanchun Guo Junfeng Zhao Jinxia Xu Wei Wang Fengshou Tian Guanyu Yang Maoping Song
作者单位:[1]Department of Chemistry, Zhengzhou University, Zhengzhou 550052, Henan, China [2]Department of Environmental Engineering, Zhengzhou Economic Management Institute, Zhengzhou 551191, Henan, China
基金项目:Fundation items: the National Natural Science Foundation of China (No.20572102)
摘    要:

关 键 词:苯甲醇 催化作用 氧化物 需氧反应
修稿时间:2006-12-052007-01-15

Aerobic Oxidation of Benzyl Alcohol Catalyzed by Cu-Mn Mixed Oxides and 2,2,6,6-Tetramethyl-piperidyl- 1-oxy1
Abstract:Heterogeneous Cu-Mn mixed oxides can mediate TEMPO-catalyzed selective oxidation of benzyl alcohol by molecular oxygen under neutral condition, and is recyclable. In the case of the molar ratio of Cu and Mn over 1, the highly-dispersed CuO inside the Cu-Mn mixed oxides is responsible for the good performances in catalytic oxidation.
Keywords:Cu-Mn oxides   2,2,6,6-tetramethyl-piperidyl-l-oxyl   aerobic oxidation   benzyl alcohol
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