Formation of iodine atoms in the heterogeneous reaction between chlorine and iodomethane |
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| Authors: | I K Larin A I Spasskii E M Trofimova L E Turkin |
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| Institution: | 1.Institute of Energy Problems of Chemical Physics,Russian Academy of Sciences,Chernogolovka, Moscow oblast,Russia |
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| Abstract: | The rate constant of the reaction between iodomethane and chlorine atoms at 323 K, measured by the resonance florescence method
under jet stream conditions as the iodine atom yield, is k
1I = (2.9±0.6) × 10−12 cm3 molecule−1 s−1. It is demonstrated experimentally that this reaction takes place mainly on the reactor wall. |
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