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Thermally induced structural transformation of polytriazoleimide to polyindoleimide
Authors:Yan Peng E  Li Qiang Wan  Yu Jing Li  Fa Rong Huang  Lei Du
Affiliation:Key Laboratory for Specially Functional Polymeric Materials and Related Technology of the Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
Abstract:A new kind of polytriazoleimide containing bisphenyl-l,2,3-triazole(BPT) was synthesized by copper-catalyzed 1,3-dipolar cycloaddition of azides and alkynes(CuAAC) and polycondensation.The thermal stability and degradation mechanism of the polytriazoleimide were investigated.The results show that the structure of BPT in polytriazoleimide transforms to phenylindole after thermal treatment,accompanying the release of N2.
Keywords:Polytriazoleimide  Structural transformation  Phenylindole  Thermal stability
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