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TG and DSC studies of filled porous copolymers
Authors:Y N Bolbukh  V A Tertykh  B Gawdzik
Institution:(1) Institute of Surface Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine, 03164, Gen. Naumov Str. 17;(2) Faculty of Chemistry, Maria Curie-Skłodowska University, Lublin, Poland, 20031, M. Curie-Skłodowska Sq. 3
Abstract:A complex approach including thermogravimetry, differential thermal analysis and differential scanning calorimetry was applied to study characteristics of non-filled and filled porous copolymers of divinylbenzene with styrene or some acrylic monomers: di(methacryloyloxymethyl)naphthalene, methacrylic ester of p,p’-dihydroxydiphenylpropane diglycidyl ether, and dimethacrylglycolethylene. High disperse silicas with the grafted methyl and silicon hydride groups in the surface layer were used as fillers. The kinetic parameters of thermal degradation for composites obtained were determined by different methods.
Keywords:chemically modified silicas  degradation kinetics  DSC  fillers  methacrylic monomers  porous copolymers  TG
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