Enantio- and regioselective iridium-catalyzed allylic hydroxylation |
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| Authors: | Gärtner Martin Mader Steffen Seehafer Kai Helmchen Günter |
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| Affiliation: | Organisch-Chemisches Institut der Ruprecht-Karls-Universita?t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany. |
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| Abstract: | The first enantioselective allylic hydroxylation to prepare branched allylic alcohols directly is described. Bicarbonate was used as nucleophile in conjunction with new single component Ir-catalysts, which are stable to air and water. Excellent regio- and enantioselectivities have been achieved with a representative set of substrates. |
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