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Spatial structure in diffusion-limited two-particle reactions
Authors:Maury Bramson  Joel L Lebowitz
Institution:(1) Department of Mathematics, University of Wisconsin, 53706 Madison, Wisconsin;(2) Departments of Mathematics and Physics, Rutgers University, 08903 New Brunswick, New Jersey
Abstract:We analyze the limiting behavior of the densitiesrgr A(t) andrgr B(t), and the random spatial structurexgr(r) = (xgr A(t).,xgr B(t)), for the diffusion-controlled chemical reaction A+Brarrinert. For equal initial densitiesrgr B(0) = rgrb(0) there is a change in behavior fromdles 4, where rgrA(t) =rgr B(t) apC/td/4, tod ges 4, where rgrA(t) =rgr b(t) apC/t ast rarr infin; the termC depends on the initial densities and changes withd. There is a corresponding change in the spatial structure. Ind < 4, the particle types separate with only one type present locally, and xgr, after suitable rescaling, tends to a random Gaussian process. Ind >4, both particle types are, after large times, present locally in concentrations not depending on type or location. Ind=4, both particle types are present locally, but with random concentrations, and the process tends to a limit.
Keywords:Diffusion-limited reaction  annihilating random walks  asymptotic densities  spatial structure  exact results
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