Die stufenweise Syntheseo,o′-methylenverbrückter Cyclohexamerer mitp-Kresol- oderP-Kresol- und 4-tert-Butylphenol-Bausteinen Vergleich mit ähnlich strukturierten Kettenoligomeren |
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Authors: | Hermann Kämmerer Günter Happel |
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Institution: | (1) Fachbereich Chemie, Universität Mainz, D-6500 Mainz, Bundesrepublik Deutschland |
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Abstract: | Two phenolic alcohols with six phenolic units in their molecules have been obtained by stepwise syntheses starting from simple phenolic derivatives. The phenolic alcohols were cyclized in a one step cyclization by boiling in a very diluted acetic acid solution. A two step cyclization of a phenolic alcohol with three phenolic units to a cyclohexamer proceeds only with poor yields. The cyclic compounds were compared with chainlike oligomers containing six phenolic units in their molecules.Herrn Prof. Dr.H. F. Mark mit allen guten Wünschen zum 85. Geburtstag gewidmet. |
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Keywords: | Chainlike phenol formaldehyde compounds Cyclohexamers with phenolic units Phenolic alcohols |
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