Mechanism of the reaction of 3,3-dimethyl-2-trimethylsiloxy-1-trimethylsilyl-1-phosphabut-1-ene with diethyl phosphite |
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| Authors: | E. A. Ishmaeva D. V. Chachkov A. Z. Alimova Ya. A. Vereshchagina V. I. Galkin |
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| Affiliation: | 1. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, Kazan, 420008, Tatarstan, Russia
2. Kazan Branch, Joint Supercomputer Center of the Russian Academy of Sciences, ul. Lobachevskogo 2/31, Kazan, 420111, Tatarstan, Russia
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| Abstract: | The reaction of a stable two-coordinate phosphorus compound, 3,3-dimethyl-2-trimethylsiloxy-1-trimethylsilyl-1-phosphabut-1-ene, with diethyl phosphite was studied in terms of the density functional theory [DFT B3PW91/6-31G(d)]. A two-step mechanism of the reaction was established. |
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