Mechanism of the reaction of 3,3-dimethyl-2-trimethylsiloxy-1-trimethylsilyl-1-phosphabut-1-ene with diethyl phosphite |
| |
| Authors: | E A Ishmaeva D V Chachkov A Z Alimova Ya A Vereshchagina V I Galkin |
| |
| Institution: | 1. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, Kazan, 420008, Tatarstan, Russia
2. Kazan Branch, Joint Supercomputer Center of the Russian Academy of Sciences, ul. Lobachevskogo 2/31, Kazan, 420111, Tatarstan, Russia
|
| |
| Abstract: | The reaction of a stable two-coordinate phosphorus compound, 3,3-dimethyl-2-trimethylsiloxy-1-trimethylsilyl-1-phosphabut-1-ene, with diethyl phosphite was studied in terms of the density functional theory DFT B3PW91/6-31G(d)]. A two-step mechanism of the reaction was established. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
