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Conductivity studies of aqueous solutions of stereoisomers of tartaric acids and tartrates. Part II: D-, L-, andmeso-tartaric acids
Authors:Marija Bešter-Rogač  Roland Neueder  Josef Barthel  Alexander Apelblat
Institution:1. Department of Chemistry and Chemical Technology, University of Ljubljana, Slovenia
2. Institut für Physikalische und Theoretische Chemie, Universit?t Regensburg, D-93040, Regensburg, Germany
3. Department of Chemical Engineering, Ben Gurion University of the Negev, Beer Sheva, Israel
Abstract:Conductivity measurements on aqueous solutions of D-tartaric acid, L-tartaric acid, andmeso-tartaric acid were performed in the temperature range 278.15–308.15 K. The equivalent limiting conductivity of the bitartrate anion, λ°(HTar-), is evaluated with regard to the primary and secondary steps of dissociation of the acids in aqueous solutions by use of the Quint and Viallard equation for unsymmetrical electrolytes.
Keywords:Temperature dependence of conductivity  ion conductivities  aqueous solutions  D-tartaric acid  L-tartaric acid            meso-tartaric acid
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