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Ultra-thin emissive molecular devices: polarized emission of Ln(III) complex films
Authors:Miki Hasegawa  Shunsuke Kunisaki  Hideki Ohtsu  Franz Werner
Affiliation:(1) Department of Chemistry and Biological Science, College of Science and Engineering, Aoyama Gakuin University, Kanagawa 229-8558, Japan;(2) Institute for Molecular Science, Okazaki 444-8585, Japan;(3) Research Center for Advanced Science and Technology, The University of Tokyo, Tokyo 153-8904, Japan
Abstract:Abstract  On ultra-thin films, Tb(III) shows polarized ff-emission in the visible wavelength region induced by intramolecular energy transfer from the photoexcited organic ligand, such as phenanthroline. Pr(III) causes polarized ππ* emission from the chromophore in the ultra-thin film (Langmuir–Blodgett film). Here, the unique optical properties of molecular devices with lanthanide complexes are summarized. Graphical Abstract   MediaObjects/706_2009_134_Figa_HTML.gif
Keywords:Lanthanide complexes  LB film  Stretched PVA film  Emission  Polarized electronic transitions
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