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Ligand-free Suzuki-Miyaura Cross-Coupling Reactions of Aryltriazenes with Arylboronic Acids |
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| Authors: | Nan Guangming Zhu Fanghua Wei Zhijun |
| Institution: | 1. Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu, Sichuan 610064, China;2. College of Chemistry and Biology, Yili Normal University, Yining, Xinjiang 835000, China;3. Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang, Shichuan 621900, China |
| Abstract: | The boron trifluoride induced Suzuki‐Miyaura cross‐coupling of aryltriazenes with arylboronic acids catalyzed by Pd(OAc)2 without added ligands has been achieved for the first time. The reactions performed at room temperature under an argon atmosphere give biaryls in good to excellent yields. It is noteworthy that the reactions were conducted under mild and ligand‐free conditions. |
| Keywords: | aryltriazenes Suzuki reaction arylboronic acids ligand‐free |
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