Synthesis,Crystal Structure,Hirshfeld Surface Analysis,and Physicochemical Study of an Anhydrous Organic Acidic Cyclohexaphosphate |
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Authors: | Ramzi Fezai Mohamed Rzaigui |
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Institution: | 1.Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte,Université de Carthage,Zarzouna,Tunisia |
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Abstract: | The new organic–inorganic hybrid 5-Cl-2-(CH3)C6H3NH3]4H2P6O18 has been synthesized by the slow evaporation method. X-ray diffraction on a single crystal shows that this acidic cyclohexaphosphate crystallized in the monoclinic space group C 2/c with a?=?33.89(11) Å, b?=?9.16(16) Å, c?=?13.68(3) Å, β?=?91.35(2)°, V?=?4244.9(19) Å3 and Z?=?4. 31P MAS-NMR and 13C CP/MAS-NMR results are in accordance with X-ray findings. Fluorescent study shows the blue photoluminescence. Furthermore, FT-IR analysis was studied and the complete vibrational assignments were done. Intermolecular interactions were analyzed using Hirshfeld surface analysis and the associated 2D fingerprint plots. |
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