Evaluation of the activation energies of elementary propagation steps in the catalytic polymerization of olefins |
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| Authors: | V A Zakharov |
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| Institution: | (1) Institute of Catalysis, Novosibirsk, USSR |
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| Abstract: | The possible relation between the activation energies of adsorption and insertion reactions and the heat of olefin adsorption for the two-step mechanism of propagation have been evaluated on the basis of calculated preexponential factors for the propagation rate constants and the experimental activation energies of propagation.
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