A Unified Interpretation of Kinetic Data on the Acid-Induced Cleavage and of Product-Analysis Data on Spontaneous Cleavage of the Mono-ol Cation μ-Hydroxo-bis[pentaamminecobalt(III)] ([(NH3)5CoOHCo(NH3)5]5+) |
| |
Authors: | Franois P Rotzinger Werner Marty |
| |
Institution: | François P. Rotzinger,Werner Marty |
| |
Abstract: | Recent work on the spontaneous (= acid-independent) cleavage of the mono-ol cation, i.e. in Cl?/ClO and NO /ClO mixed-electrolyte media has established (by analysis of anion-competition experiments) the existence of reactive ion pairs of the mono-ol cation with Cl? and NO . Their existence must be allowed for in the analysis of the rate data for the acid-induced cleavage (pH 0–1) of the mono-ol cation in these mixed-electrolyte media. Thus, previous data for acidic Cl?/ClO media have been re-interpreted in this work, and new data for NO /ClO media have been analyzed in the same sense. This analysis removes an apparent discrepancy in the orders of magnitude of ion aggregate stability constants between the mono-ol and similar binuclear cations. |
| |
Keywords: | |
|
|